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Thermal oxidizers are a type of industrial equipment used in manufacturing and other industrial processes to reduce emissions of harmful organic solvents, air pollutants, and other industrial emissions. Using extreme high temperatures to trigger a combustion reaction, the emissions undergo thermal oxidization, transforming the complex organic solvents into CO2 and H2O.
Oxidizers, also known as incinerators or after-burners, are used at many manufacturing facilities worldwide. During the manufacturing process for tape or adhesives, as an example, solvents are released into the air, collected and transported via large industrial ductwork powered by large fans, until they reach their target destination: a thermal oxidizer. The contaminated gases pass through a temperature-controlled environment, which is powered by a burner and combustion blower, reaching temperatures around 1400°F - 1450°F.
At this temperature, in the presence of oxygen, the gaseous chemicals undergo an oxidation reaction, destroying the pollutants before releasing the exhaust to atmosphere.
The most basic type of oxidizer is a direct-fired, also known as an incinerator or afterburner. As the simplest type of oxidizer, it does not include any heat recovery, heat exchanger, scrubber, adsorbent, or catalyst material. It offers the lowest upfront capital investment cost, but requires the most energy to operate. Other oxidizer designs implement a heat recovery mechanism or catalyst to reduce the required reaction temperature.
Due to the lack of heat recovery, this design is best suited for applications with a very high concentration of VOCs or applications that only need to run for a small percentage of time. Often times, the direct-fired used in combination with a leading VOC concentrator. As with most oxidizers, the direct-fired type offers a destruction efficiency of 98%-99%.
A more thermally-efficient design, the Recuperative Thermal Oxidizer passes the hot exhaust gas through a heat exchanger, heating the incoming process air. This way, the burner in the oxidizer only needs to provide a fraction of the heat load required for a successful combustion reaction. The heat exchanger and additional ductwork costs more money upfront, but the recuperative design requires less natural gas during operation.
This model of thermal recuperative oxidizer uses a high-efficiency heat exchanger to heat the incoming process air from 200°F to ~700°F, reducing the required temperature rise over the burner to reduce natural gas usage and lower operating costs. The recuperative oxidizer is a very common type of oxidizer in industry, due to the favorable energy usage payback in high-use applications.
A more complex design, the catalytic oxidizer uses a precious metal catalyst, such as Platinum, Palladium, and Rhodium, within the combustion chamber to lower the required reaction temperature. Whereas a direct-fired oxidizer would require temperatures near 1400°F - 1450°F, in the presence of a catalyst, the same reaction can complete at a much lower temperature: 600°F - 650°F. The lower firing temperature requires less natural gas than both a direct-fired a recuperative oxidizer. It also comes in a regenerative catalytic design (RCO).
The downside of CTOs and RCOs is a higher capital cost and potentially high maintenance costs. The precious metal catalysts are often very expensive and prone to fouling. Once the catalyst is sufficiently fouled, it must be replaced or the reaction temperature must be increased. When selecting an oxidizer, an analysis of VOCs and pollutants must be completed to determine likelihood of fouling.
Best suited for large air volumes where a concentrator cannot be used, the RTO boasts the best thermal efficiency of all oxidizers. Using two or three beds of ceramic media, the RTO design uses waste heat stored in the ceramic media to heat the incoming air to temperatures of 1300+°F, very near to the oxidation temperature. Even at reaction temperatures of 1450°F, the RTO burner may only need to heat the air 50-100°F.
The standard three-tower RTO design allows for one tower to be exothermic, or giving off heat to the incoming air, while another tower will be endothermic, or absorbing the waste heat from the exiting air, and one tower to be purging air at any time. Purge air is sent through the combustion chamber to ensure all VOCs are captured and destroyed before being released to atmosphere.
Currently being installed in 2017, Honda's newest paint manufacturing facility will feature both a regenerative thermal oxidizer (RTO) and a thermal recuperative oxidizer with fluidized bed concentrator (FBC) provided by TKS Industrial. The RTO will be used for control of the paint oven's hazardous air pollutant (HAP) emissions, while the recuperative oxidizer will control VOC emissions from the Acura and Accord paint booths. Honda plans to operate their thermal oxidizers in parallel for 24 hours a day, six days a week.
Slated to start production in early 2018, Honda's newest oxidizers will net energy savings over their older VOC control equipment. Honda has already earned awards for reducing air pollution at their plant in Lincoln, Alabama. Honda's team in Marysville, Ohio hopes to follow suit.
Kia Motors selected a large regenerative oxidizer (RTO) to control both their paint booth and cure oven VOC emissions. A three-tower 50,000 CFM unit is one of the largest RTOs that TKS has ever installed. Kia elected to save money by combining the paint booth and oven emissions into the same VOC control equipment. The RTO is well suited for Kia's use with low concentration VOCs coming from their oven, and running three shifts daily, and six-to-seven days per week, near continuous operation.
The downside from a maintenance perspective is tar. When the hot oven air meets the cool booth air, the gaseous tar products in the oven exhaust condense and stick to the ductwork, the fans, and the RTO's ceramic media bed. As a result, Kia achieves lower air volume throughput as it become clogged with tar and the ceramic media requires replacing every 3-4 years instead of every 5-6 years as is typical.
This Japanese Automaker selected a recuperative thermal oxidizer with VOC concentrator to treat their VOC emissions from both paint spray booths and heated flash offs. A pair of heat exchangers use the post-oxidation waste heat to preheat the VOC-laden air before it enters the thermal oxidizer and heat the air for the carbon desorption loop.
This Japanese Automotive OEM, the largest worldwide, has chosen for TKS to install a total of five (5) oxidizers at its Georgetown manufacturing facilities since 2014. While the first oxidizers installed were simple direct-fired oxidizers, the customer has since progressed to thermally recuperative oxidizers with not one, but two heat exchangers (HEXs). They have drastically reduced their emissions and carbon footprint, with goals for the entire campus to be carbon neutral by 2025.
During construction of their new manufacturing plant in 2012, Nissan selected two 30,000 CFM regenerative oxidizers (RTOs). One RTO services the combined oven exhaust while the second RTO services the VOC exhausts from two clear coat paint booths. Regenerative Oxidizers are ideal for Nissan's low VOC concentrations and long, continuous operation.
This dual-RTO approach comes with slightly increased upfront capital investment, but avoids the tar issues that Kia is experiencing with their single RTO implementation. As today’s most widely accepted air pollution control technology across nearly every industry, Nissan's Regenerative Oxidizer, commonly referred to as an RTO, is robust, versatile, and extremely thermally efficient – with heat recovery efficiency reaching up to 97%. This is achieved through the storage of waste heat via structured ceramic blocks.
3-D Animation of an RTO @ 190,000 SCFMhttps://youtu.be/RVHWp1pvgsA
Keeping the Air Clean with an Oxidizer #TKSJanuary 10, 2016
Excited. Our new recuperative oxidizer will be up and running todayJanuary 2, 2016
Don't forget to schedule your oxidizer's PM over shutdown #TKSDecember 13, 2015
TKS employs the industry's leading experts on environmentally-friendly oxidizer solutions. Whether you need a simple direct-fired oxidizer, a large RTO, or fluidized bed concentrator with recuperative oxidizer, TKS' engineers and experts are here to give you the best advice.
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In the classic three-tower design, an RTO has three phases of operation. Each tower moves sequentially through endothermic, exothermic, and purge cycles. In the first cycle, ceramic media in the tower absorbs heat from the post-combustion gas as it comes down to exhaust. In the second cycle, the media now releases heat, warming the pre-combustion gases as they move up towards the burner. In the third cycle, fresh air is purged through the tower to the burner, ensuring no VOCs are accidentally exhausted.
The cost of an oxidizer can vary from $100,000 USD to over $500,000 USD, depending on system size, installation location, and the type selected. Each oxidizer can be shipped in pieces to the job site for third-party installation, or TKS offers a turn-key solution where every aspect of your project from design, fabrication, installation, commissioning, start-up and stand-by service is included. The scope of each project is different and we will adjust the scope to meet your budget and needs.